基多电解质:在离子电池中制备,性能和使用
Muhammad Syukri Mohamad Misenan1, Rolf Hempelmann2, Markus Gallei3,4
1Department of Chemistry, College of Arts and Science, Davutpasa Campus, Yildiz Technical University, 34220 Istanbul, Turkey.
Polymers
|July 14, 2023
概括
基于的聚合离子液 (PIL) 为离子电池提供稳定,不易挥发的固体电解质. 灵活的聚合物骨干增强导电性,为先进的储能解决方案和回收利用铺平了道路.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 电化学 电化学 电化学
背景情况:
- 离子液体 (ILs) 提供高稳定性和离子流动性,但存在泄漏和粘度问题.
- 聚合离子液 (PILs) 将IL特性与聚合物特性相结合,产生像非挥发性固体电解质这样的材料.
- 化合物在工业上至关重要,其应用范围从阻燃剂到肥料.
研究的目的:
- 审查基于的聚合离子液体 (PILs).
- 讨论它们的合成,特性和相对于基PIL的比较优势.
- 突出其作为离子电池 (LIB) 中聚合物电解质的潜力.
主要方法:
- 对基于的PIL合成路径和特性进行文献综述.
- 分析结构属性关系,重点关注骨干灵活性和导电性.
- 基于的PIL与基于的对应物进行比较.
主要成果:
- 基于的PIL是LIB的有希望的固体电解质,提供非挥发性和非易燃性.
- PIL中的柔性聚合物骨干与改善的离子导电性相关.
- 该综述总结了化学结构,并讨论了优缺点.
结论:
- 基于的PIL为LIBs中的传统液体电解质提供了可行的替代方案.
- 优化骨干灵活性是提高其作为聚合物电解质性能的关键.
- 未来的研究应该探索从废物中回收以实现可持续的PIL发展.
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