双甲二甲基甲基基乙烯-初级氨基聚合物-多聚合物 (ε-caprolactone) 网络:合成和表征
Katalin Czifrák1, Csilla Lakatos1, Gabriella Szabó1
1Department of Applied Chemistry, University of Debrecen, Egyetem tér 1, H-4032 Debrecen, Hungary.
Polymers
|July 14, 2023
概括
研究人员开发了具有形状记忆特性的新型交联聚氨环氧 (PU-EP) 聚合物. 添加furfurylamine可为先进材料应用提供可调节的热可逆交叉链接.
科学领域:
- 聚合物化学 聚合物化学
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
背景情况:
- 开发具有定制性质的先进聚合物网络对于下一代材料至关重要.
- 交联聚合物提供增强的机械强度和热稳定性.
- 形状记忆聚合物 (SMPs) 显示出在刺激时恢复原始形状的能力.
研究的目的:
- 合成和描述新的交联聚氨环氧 (PU-EP) 聚合物系统.
- 调查氨基同类分子 (furfurylamine和ethanolamine) 对PU-EP网络形成和特性的影响.
- 探索这些PU-EP系统在形状记忆应用中的潜力.
主要方法:
- 合成NCO终结的聚氨预聚合物使用聚乙烯二醇和1,6-甲二酸.
- 双甲基 (DGEBA) 的二甲基乙烯 (diglycidyl ether) 与利胺 (FA) 或乙醇胺 (EA) 的氧化.
- 将PU预聚合物与DGEBA-胺聚合物交叉链接,然后使用ATR-FTIR,DSC,DMA和SEM进行表征.
主要成果:
- 成功准备了交叉连接的PU-EP网络,其中尿键作为网点.
- 乙胺促进了新的尿键的形成,而胺则引入了热可逆的迪尔斯-阿尔德合.
- 动态机械分析证实了交联结构,并揭示了特定PU-EP组合中的形状记忆行为.
结论:
- 合成的PU-EP聚合物具有可调节的交叉链接和形状记忆特性.
- 瑞胺的结合允许通过热可逆结合微调形状记忆行为.
- 这些发现为开发具有可控制形状恢复的先进智能材料开辟了道路.
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