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Updated: Jul 23, 2025

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
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Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction

Published on: April 10, 2018

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控制合成ACo2O4 (A = Fe,Cu,Zn,Ni) 作为尿素电解的环保电催化剂

Ping Li1, Yanhong Wang1, Xiaoqiang Du1

  • 1School of Chemistry and Chemical Engineering, North University of China, Xueyuan road 3, Taiyuan 030051, People's Republic of China. duxq16@nuc.edu.cn.

Dalton transactions (Cambridge, England : 2003)
|July 14, 2023
PubMed
概括

研究人员开发了一种新的铜氧化物 (CuCo2O4) 催化剂,通过尿素电解有效生产气. 这种催化剂通过使尿素氧化反应 (UOR) 与氧化演化反应 (OER) 相比,在较低的潜力下显著降低能耗.

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Simple Methods for the Preparation of Non-noble Metal Bulk-electrodes for Electrocatalytic Applications09:18

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Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production08:40

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Alkylation of β-Ketoester Enolates: Acetoacetic Ester Synthesis01:07

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Acetoacetic ester synthesis is a method to obtain ketones from alkyl halides and β-keto esters. The reaction occurs in the presence of an alkoxide base that abstracts the acidic proton of the β-keto esters. The step results in an enolate ion which is doubly stabilized. The enolate then reacts with an alkyl halide via the SN2 process to produce an alkylated ester intermediate with a new C–C bond. The hydrolysis of the intermediate, followed by acidification, results in an...
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Catalysis

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Carbonyl compounds and primary amines undergo reductive amination first to produce imines, followed by secondary amines in the same reaction mixture, using selective reducing agents like sodium cyanoborohydride or sodium triacetoxyborohydride. Reductive amination produces different degrees of substitution of amines depending on the starting amine substrate.
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Amides are synthesized by treating carboxylic acids with amines in the presence of dehydrating agents like dicyclohexylcarbodiimide (DCC).
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