体表面电荷对干燥裂纹的影响
Sanket Kumar1,2,3, Madivala G Basavaraj2,3, Dillip K Satapathy1,3
1Soft Materials Laboratory, Department of Physics, IIT Madras, Chennai 600036, India.
Langmuir : the ACS journal of surfaces and colloids
|July 14, 2023
概括
合体干燥裂纹因粒子电荷而异. 带正电荷的合体形成更宽,更宽的裂,比负电荷的合体更快地生长,受粒子相互作用的影响.
科学领域:
- 体科学是一门学科.
- 材料科学是一种材料科学.
- 表面化学 表面化学
背景情况:
- 在干燥过程中,合体沉积物中形成了干燥裂.
- 裂纹模式受材料特性和干燥条件的影响.
- 了解裂纹形成对于材料的稳定性和应用至关重要.
研究的目的:
- 研究合体极性和表面电荷密度对干燥裂核和生长动力学的影响.
- 为了将裂纹模式与粒子排列和相互作用相关联.
主要方法:
- 控制干燥具有不同表面电荷的合体悬浮液.
- 对裂纹图案 (间距,开口) 的微观分析.
- 随着时间的推移,裂生长的动态分析.
主要成果:
- 与负电荷体沉积物相比,正电荷体沉积物表现出较高的裂间距和开口.
- 在正电荷粒子沉积物中,裂生长动力学更快.
- 降低表面电荷密度会增加裂间距,开口和扩张速度.
结论:
- 体表面电荷和极性显著影响干燥裂纹形成和动力学.
- 由基板-粒子和粒子-粒子相互作用驱动的粒子排列,决定了不同的裂纹模式.
- 表面电荷密度是控制干燥合体裂纹特性的关键参数.
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