关于RP-3/空气燃烧的点火延迟和反应机制的研究 添加C6F12O
Binbin Yu1,2, Xinsheng Jiang1, Changhua Zhang3
1Petroleum, Oil & Lubricants Department, Army Logistics Academy, Chongqing 401331, China.
ACS omega
|July 17, 2023
概括
诺维克1230通过改变点火延迟时间,有效地抑制RP-3喷气式燃料火灾. 这项研究提供了一个修改后的化学动力学模型来分析C6F12OO.
科学领域:
- 化学动力学 化学动力学
- 燃烧科学 燃烧科学
- 灭火技术 灭火技术
背景情况:
- 在中国,RP-3喷气式燃料是主要的航空燃料,具有很大的火灾危险性.
- C6F12O (Novec 1230) 是一种具有较低环境影响的有效灭火剂.
研究的目的:
- 研究C6F12O在抑制RP-3喷气式燃料火灾中的应用.
- 测量C6F12O/空气和RP-3/空气混合物加C6F12O的点火延迟时间 (IDT).
- 开发和验证C6F12O抑制RP-3喷气燃料燃烧的化学动力学模型.
主要方法:
- 使用冲击管测量点火延迟时间.
- 通过实验确定了温度,C6F12O度和RP-3静脉测量对IDT的影响.
- 改进和整合的C6F12O和RP-3喷气式燃料的化学动力机制.
主要成果:
- C6F12O的IDT为500-900μs,温度敏感性低于常见燃料.
- C6F12O对RP-3喷气式燃料IDT的影响取决于温度,C6F12O度和燃料固态度.
- 综合化学运动模型准确地预测了实验IDT数据.
结论:
- C6F12O证明了RP-3喷气式燃料火灾抑制的潜力.
- 经过验证的化学动力学模型为进一步分析C6F12O的燃烧抑制机制提供了基础.
- 这项研究支持开发更安全的航空燃料灭火策略.
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