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相关概念视频

Preparation and Reactions of Sulfides02:26

Preparation and Reactions of Sulfides

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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
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Formation of Complex Ions03:45

Formation of Complex Ions

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A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
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Batteries and Fuel Cells03:12

Batteries and Fuel Cells

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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相关实验视频

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Screening of Coatings for an All-Solid-State Battery Using In Situ Transmission Electron Microscopy
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合理设计的可处理溶液的导电碳添加剂涂层,用于硫化物为基础的全固态电池.

Nohjoon Lee1, Jieun Lee1, Taegeun Lee1

  • 1School of Chemical and Biological Engineering and Institute of Chemical Processes, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 08826, Republic of Korea.

ACS applied materials & interfaces
|July 17, 2023
PubMed
概括

研究人员开发了一种新的氧化 (ZnO) 涂层,用于硫化基全固态电池 (ASSB) 中的碳纤维导电剂. 这种涂层通过防止固体电解质分解来提高电池性能和寿命.

关键词:
所有固态电池都是固态电池.导电碳添加剂的导电性碳添加剂溶解热合成的溶解热合成硫化物是固体电解质的电解质.表面涂层是一种表面涂层.

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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 储能 储能 储能 储能 储能 储能

背景情况:

  • 基于硫化物的全固态电池 (ASSB) 为下一代储能提供高安全性和能量密度.
  • 在ASSB阴极中的导电剂可以降解固体电解质,限制电池寿命.

研究的目的:

  • 开发一种新型导电剂,最大限度地减少ASSB中的固体电解质分解.
  • 提高硫化物基ASSB的循环性能和速度能力.

主要方法:

  • 在蒸汽培养的碳纤维上涂上可溶液处理的氧化 (ZnO).
  • 使用改性传导剂制造ASSB的制造和电化学测试.
  • 对界面接触和电解质分解的分析.

主要成果:

  • 涂有ZnO的碳纤维有效地减少了导电剂和固体电解质之间的直接接触.
  • 具有最佳ZnO涂层的ASSB显著提高了循环性能和速度能力.
  • 增强的性能归因于抑制固体电解质分解.

结论:

  • 控制复合材料阴极中的粒子间接触对于减轻硫化物基ASSB的界面降解至关重要.
  • O涂层策略是一种可行的方法,可以提高ASSB的电化学特性和寿命.