两个维的金属二化物中的铁磁性是由孔剂诱导的
Ruishen Meng1, Michel Houssa2,3
1Department of Physics and Astronomy, KU Leuven, Leuven, 3001, Belgium. ruishen.meng@kuleuven.be.
Scientific reports
|July 17, 2023
概括
二维的和二化物可以通过孔造使其具有铁磁性. 特定的缺陷和和硫等剂可以在这些非磁性材料中诱导这种磁性行为.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 固态化学 固态化学
背景情况:
- 二维 (2D) 材料具有独特的电子和磁性特性.
- 化 (PbBr2) 和化 (HgBr2) 本质上是非磁性的二维材料.
- 孔是诱导非磁性系统中磁性的潜在策略.
研究的目的:
- 调查通过洞 doping 诱导2D PbBr2 和 HgBr2 铁磁性的可能性.
- 分析内在和外在缺陷在实现洞和铁磁性的作用.
- 在这些二维二化物中确定适合稳定的铁磁顺序的剂.
主要方法:
- 旋转偏振的第一原则计算.
- 密度函数理论 (DFT) 框架.密度函数理论框架.
- 分析电子结构和磁性特性.
主要成果:
- 在密度 > 10^13 cm^-2 的孔可以诱导 2D PbBr2 和 HgBr2.2 中稳定的铁磁顺序.
- Pb/Hg空缺和Br抗体可以作为p型兴奋剂,尽管Br抗体是深受体.
- 替代Pb/Hg和S替代Br在HgBr2中产生浅的受体状态,促进铁磁性.
结论:
- 在2D中,铁磁性可以通过洞 doping 可控地诱导 PbBr2 和 HgBr2.
- 缺陷工程和特定的剂选择对于实现所需的磁性属性至关重要.
- 这些发现为新的二维磁性材料开辟了道路.
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