带有表面活性剂的双层薄液体薄膜的不稳定性和破裂
Shu Yang1, Satish Kumar2, Cari S Dutcher1,2
1Department of Mechanical Engineering, University of Minnesota, Minneapolis, MN 55455, USA. cdutcher@umn.edu.
Soft matter
|July 18, 2023
概括
将特定的表面活性剂添加到薄液体薄膜中可以显著提高其稳定性,延迟破裂的时间高达十倍. 优化表面活性剂度是利用稳定马兰戈尼应力用于消防泡等应用的关键.
科学领域:
- 流体动力学 流体动力学
- 表面科学是一门科学.
- 材料科学是一种材料科学.
背景情况:
- 双层薄膜对于消防泡和涂层至关重要.
- 表面活性剂对薄膜稳定性的影响是复杂的,并未完全理解.
- 以前的模型经常包括混物理效应.
研究的目的:
- 隔离和量化表面活性剂对双层薄膜稳定性的影响.
- 为了建模接口和表面活性剂度的合动态.
- 研究延迟范德瓦尔斯驱动破裂的机制.
主要方法:
- 应用了滑近似来导出非线性演化方程.
- 在液体-液体和液体-空气接口上都包含不溶性表面活性剂吸附.
- 利用线性稳定性分析和非线性模拟.
主要成果:
- 表面活性剂在两个接口上吸附,可以使破裂时间增加一个数量级.
- 最佳表面活性剂度对于通过马兰戈尼应力有效稳定至关重要.
- 粘度比显著影响马兰戈尼应力方向和强度.
结论:
- 表面活性剂的选择和度对于提高薄膜稳定性至关重要.
- 了解马兰戈尼应力动态指导表面活性剂设计,以提高性能.
- 这些发现适用于开发更好的灭火泡和涂料.
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