在现场测量精细化气溶颗粒的表面张力
Masao Gen1, Akihide Hibara1,2, Phuong Nguyet Phung3
1Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980-8577, Japan.
The journal of physical chemistry. A
|July 18, 2023
概括
测量气溶颗粒表面张力对于云形成至关重要. 结合电动平衡和光散射的新方法提供了现场测量,揭示了尺寸和组成对表面张力的影响.
科学领域:
- 大气化学 大气化学
- 物理化学 物理化学
- 气溶科学 气溶科学
背景情况:
- 气溶颗粒的表面张力影响云滴激活.
- 直接测量薄化气溶颗粒的表面张力在实验上具有挑战性.
研究的目的:
- 开发和验证一种新的现场方法来测量气溶颗粒表面张力.
- 为了研究粒子大小,组成和相对湿度对表面张力的影响.
主要方法:
- 连接一个线性四极电动平衡 (EDB) 与准弹性光散射 (QELS).
- 使用大气相关的无机和有机液滴进行验证.
- 测量尺寸依赖和相对湿度依赖的表面张力.
主要成果:
- EDB-QELS方法提供可靠的表面张力测量 (∼50-90 mN m-1).
- 含二甲基硫酸盐的NaCl滴的表面张力随着尺寸的减少 (∼5-18μm) 增加.
- 在混合硫酸盐和聚乙烯糖醇滴中观察到液体-液体相分离.
- 在水中溶解的有机碳显著降低了环境气溶衍生的水滴的表面张力.
结论:
- 新的EDB-QELS技术可以准确地在现场测量气溶颗粒的表面张力.
- 颗粒大小,成分 (表面活性物种,有机碳) 和相对湿度显著影响气溶表面张力.
- 这些发现对于理解气溶云相互作用和改善气候模型至关重要.
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