汉森可溶性参数用于直接处理表面和界面现象.
Masakazu Murase1, Daisuke Nakamura1
1Toyota Central R&D Laboratories, Inc., Nagakute, Aichi 480-1192, Japan.
Langmuir : the ACS journal of surfaces and colloids
|July 18, 2023
概括
这项研究引入了一个新的方程,用汉森溶解度参数 (HSP) 来估计表面和界面张力. 这种方法成功地预测了聚合物湿透性,为更广泛的应用统一了散装和表面特性.
科学领域:
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
- 聚合物科学 聚合物科学
背景情况:
- 汉森溶解度参数 (HSP) 传统上描述了聚合物和溶剂的批量性质.
- 将表面和界面现象集成到HSP框架中,对于全面的材料表征至关重要.
- 现有的方法缺乏统一的方法来连接散体特性与表面能量和张力.
研究的目的:
- 在HSP框架内开发一种新的方程来估计表面张力,表面能量和界面张力.
- 为了弥合散装材料特性和表面/接口行为之间的差距.
- 扩大广泛的HSP数据库适用于与表面相关的现象.
主要方法:
- 提出了一个新的方程来计算表面和界面张力/能量,基于散装HSPs.
- 探针液体在聚合物上的接触角度估计使用开发的方程.
- 将估计的接触角与通过滴法获得的实验测量值进行比较.
- 在一系列液体表面张力,固体表面能量和界面张力中验证了方程的预测能力.
主要成果:
- 拟议的方程证明了足够的相关性,用于实际的湿度预测.
- 在估计和测量接触角度之间观察到良好的一致性.
- 这些相关性证实了方程对各种表面和界面张力值的预测准确性.
- 成功统一了表面/接口属性与散装HSP,使得两个方向的属性估计.
结论:
- 修改后的HSP框架有效地整合了表面和界面现象.
- 表面特性现在可以从散装特性可靠地估计,反之亦然.
- 该HSP数据库的实用性显著扩大,包括表面和接口应用.
- 这种方法有助于理解和设计复杂的多组件和多阶段系统.
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