页岩气储中的水吸附及其孔隙结构依赖性
Weidong Xie1,2,3, Hua Wang1,2, Si Chen1,2
1Key Laboratory of Tectonics and Petroleum Resources of Ministry of Education, China University of Geosciences, Wuhan 430074, China.
Langmuir : the ACS journal of surfaces and colloids
|July 18, 2023
概括
页岩中的水吸附受到孔隙结构,有机物质和矿物学的影响. 这些因素控制了初级和二级吸附过程,这对于了解页岩气储库至关重要.
科学领域:
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
- 石油工程是石油工程中的一个.
背景情况:
- 了解页岩中的水分子行为对于资源管理,经济可行性和环境保护至关重要.
- 页岩气储库包含复杂的孔隙系统,影响流体行为.
研究的目的:
- 为了研究Longmaxi页岩上水蒸气的吸附特性.
- 确定主要和次要吸附过程及其控制因素.
主要方法:
- 在页岩样本上对水蒸气吸附的实验测试.
- 使用同热吸附模型 (Dent, Langmuir, Freundlich) 拟合实验数据.
- 分析有机物质,矿物学和毛孔结构的影响.
主要成果:
- 丹特模型准确地描述了整体吸附,而兰穆尔和弗洛因利希模型分别适用于初级和二级吸附.
- 水蒸气吸附主要由页岩的孔积和特定表面积 (SSA) 控制.
- 半孔结构显著影响吸附能力,有机物中的微孔驱动初级吸附.
结论:
- 页岩的孔隙结构是有机物和粘土矿物相互作用的结果,控制着水蒸气吸附.
- 特定的表面积和毛孔大小分布是影响吸附行为的关键参数.
- 这些发现有助于更好地了解页岩气储库中的水吸附机制.
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