用于高性能有机太阳能电池的生物可再生溶剂
Julianna Panidi1, Eva Mazzolini1,2, Flurin Eisner3
1Department of Chemistry & Centre for Processable Electronics, Imperial College London, London W12 0BZ, U.K.
概括
这项研究探讨了有机太阳能电池的绿色溶剂. 使用可生物再生的2-甲基四水 (2MeTHF) 和环甲基乙烯 (CPME) 可使有机光伏 (OPV) 设备在没有有毒添加剂的情况下进行高效的加工.
科学领域:
- 材料科学 材料科学 材料科学
- 可再生能源可再生能源是可再生能源.
- 有机电子 有机电子
背景情况:
- 有机光伏 (OPV) 设备通过非富勒烯接受器 (NFAs) 实现高功率转换效率 (PCE).
- 目前的高性能OPV依赖于有毒的,以石油为基础的溶剂,阻碍了可持续的大规模制造.
- 开发更绿色的加工方法对于商业化OPV至关重要.
研究的目的:
- 调查生物可再生溶剂的使用,以处理OPV活性层.
- 为了减少OPV制造对环境的影响和碳足迹.
- 为了展示使用可持续溶剂和材料制造的高性能OPV.
主要方法:
- 处理供体:使用生物可再生溶剂2-甲基四二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二二
- 使用聚合物捐赠体 (PTQ10和FO6-T) 与Y系列NFA (Y12),需要最小的合成.
- 在没有在活性层中添加额外的添加剂的情况下评估OPV性能.
主要成果:
- 使用2MeTHF作为处理溶剂实现了高PCE.
- PTQ10:Y12混合物达到14.5%的PCE.
- FO6-T:Y12混合物达到了11.4%的PCE.
结论:
- 像2MeTHF这样的生物可再生溶剂可以有效地在没有添加剂的情况下处理OPV活性层.
- 这种方法促进了有机太阳能电池的大规模和环保的制造.
- 这项研究为OPV技术的可持续商业化铺平了道路.
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