聚纤维的拉伸强度估计在结构形成之前通过分子链延伸
Ren Tomisawa1, Mutsuya Nagata1, Yumu Otsuka1
1Faculty of Textile Science and Technology, Shinshu University, 3-15-1 Tokida, Ueda, Nagano, 386-8567, Japan.
Scientific reports
|July 20, 2023
概括
聚乙烯基甲酸纤维中的高分子量链承受了最多的拉力. 这一发现与绘制过程中的纤维结构发展与最终纤维强度相关联.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 物理化学 物理化学
背景情况:
- 连续绘制对于开发纤维结构至关重要.
- 了解快速时间尺度上的纤维发展对于材料性能优化至关重要.
研究的目的:
- 为了研究纤维结构在连续绘制中以小于百万秒的时间尺度进行的发展.
- 为了将结构变化与聚乙烯二甲纤维的机械性能相关联.
主要方法:
- 利用激光照射加热和同步龙X射线源进行实时观测.
- 采用广角X射线衍射 (WAXD) 和小角X射线散射 (SAXS) 分析.
- 检查的聚乙烯二甲) 纤维具有不同的分子量在同等拉力应力下.
主要成果:
- 观察到在结点和最终纤维强度的微光衍射的d-间距之间的相关性.
- 证明了承受拉力应力的分子链也能承受最终纤维大部分拉力负荷.
- 确定分子质量超过23000g/mol的分子链承受了大部分拉力.
结论:
- 在绘制过程中纤维结构的发展与分子链的承载能力直接相关.
- 分子重量显著影响拉拉的聚合物纤维内的应力分布.
- 这项研究提供了通过受控绘制过程优化聚合物纤维强度的见解.
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