基于Redox定位的中性水性流电池,具有高能量密度和低成本
Su Yan1,2, Songpeng Huang3, He Xu1,2
1Institute of Energy Storage Technology, Changsha University of Science & Technology, Changsha, 410114, P.R. China.
ChemSusChem
|July 21, 2023
概括
这项研究通过使用单分子还原向反应来提高能量密度来增强中性水流电池. 开发的普鲁士蓝铁/硫电池为可再生能源储能提供了超长的寿命和低成本.
科学领域:
- 电化学和能量储存 电化学和能量储存
- 材料科学用于可再生能源.
背景情况:
- 中性水流电池为可再生能源提供安全,可扩展的能源存储.
- 铁化物/铁化物 ([Fe(CN) 6-3-4-) 是一个有前途的氧化还原媒介,但由于溶解度和能量密度低而受到限制.
- 提高能源密度对于这些系统的商业可行性至关重要.
研究的目的:
- 为了显著提高[Fe(CN) 6-3/4-基阴解质的能量密度.
- 开发一种稳定且具有成本效益的中性水流电池,用于大规模储能.
- 为了研究单分子还原向反应 (SMRT) 在电池性能中的作用.
主要方法:
- 结合反离子效应与SMRT反应,涉及[Fe(CN) 6]3-/4-和普鲁士蓝 (PB) /普鲁士白 (PW).
- 在流电池系统中使用了缩的K2S解.
- 测试了开发的电池的长期循环稳定性和容量保留.
主要成果:
- 阴解体的实际能量密度从10.5增加到92.8Wh/L.
- 证明了一种基于SMRT的中性水性PB-Fe/S流电池,使用寿命超过7000个周期 (4500小时).
- 通过SMRT实现了超低的电解质成本 (19.26 kWh-1美元) 和7000个循环后181.8%的容量保留.
结论:
- SMRT反应显著提高中性水流电池的能量密度和性能.
- 该PB-Fe/S流电池表现出卓越的循环寿命和成本效益.
- 这项技术对可再生能源的电网规模存储具有很大的前景.
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