作为甲非氧化合的催化剂的 pt/CeO:氧化再生
Hao Zhang1, Valery Muravev1, Liang Liu1
1Laboratory of Inorganic Materials and Catalysis, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, 5600 MB Eindhoven, The Netherlands.
The journal of physical chemistry letters
|July 21, 2023
概括
对于直接非氧化甲合的有效催化剂至关重要. 在 (CeO2) 上分离的 (Pt) 最初会激活甲,但烧结会导致失活. 再生和合金形成是持续生产乙烯的关键.
科学领域:
- 催化剂是一种催化剂.
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 直接无氧化合为甲升级提供了一个有希望的途径.
- 商业化受限于对高效催化剂的需求.
- 在Ceria (Pt/CeO2) 上与孤立的Pt物种最近引起了人们的兴趣.
研究的目的:
- 在非氧化甲合条件下研究CeO2上孤立的Pt中心的催化作用和稳定性.
- 了解失活机制,并探索Pt/CeO催化剂的再生策略.
- 为了确定在长时间反应期间负责甲激活的活性相.
主要方法:
- 火焰喷雾热解 (FSP) 用于催化剂制备.
- 在800°C,无氧化甲合反应发生.
- 使用氧气进行现场再生.
主要成果:
- 在CeO2上的孤立的Pt位点最初会激活甲,但在800°C时会烧结,从而减少乙烯和乙产量.
- 在氧气中的in situ再生策略有效地重新分散聚合的Pt.
- 孤立的Pt中心仅在初始阶段活跃;在长时间的反应中,CePt合金成为活跃阶段.
结论:
- 在非氧化甲合中,通过Pt烧结去活化催化剂是孤立的Pt/CeO2的一个重大挑战.
- 在现场再生提供了一种可行的方法来恢复催化剂活性.
- 在恶劣的反应条件下,形成CePt5合金对于持续的甲激活和升级至关重要.
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