零维化物具有ns2电子 (Sb3+) 激活,产生广泛的光发光
An Hou1, Liubing Fan1, Yan Xiong2
1The Beijing Municipal Key Laboratory of New Energy Materials and Technologies, School of Materials Sciences and Engineering and Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China.
Inorganic chemistry
|July 21, 2023
概括
合成了三种具有独特结构的新型有机-无机金属化物 (OIMH). 用Sb3+进行兴奋剂显著增强发光,导致在固态照明中的潜在应用.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 光物理学的光学物理学
背景情况:
- 有机-无机金属化物 (OIMHs) 具有多样化的晶体结构和有价值的半导体特性.
- 探索新型OIMH对于推进具有定制光电子功能的材料至关重要.
研究的目的:
- 合成和描述三个新的有机-无机金属化物 (OIMHs).
- 研究这些新型材料的发光特性,特别是在兴奋剂后.
- 评估它们在固态照明中的应用潜力.
主要方法:
- 三种新型OIMH的合成和晶体分析: (PPA) 6InBr9, (PBA) 2SbBr5和 (PBA) 2SbI6.
- 测量光带间隙和光发光谱的测量.
- 研究Sb3+兴奋剂对发光特性的影响以及制造用于发射白光的装置.
主要成果:
- 三个具有零维 (0D) 结构,八面体二面体和1D链的新型OIMH成功合成和表征.
- (PPA) 6InBr9表现出明亮的色光辐射,在Sb3+兴奋剂后,光发光量产率从9.2%增加到53.0%.
- 一个白色发光二极管 (WLED) 使用化 (PPA) 6In0.99Sb0.01Br9进行制造,实现了高颜色染指数92.3.3.
结论:
- 合成的新型OD OIMHs显示出有前途的发光特性.
- Sb3+ 注显著提高了 (PPA) 6InBr9.9 的发光效率.
- 这些发现突显了这些新型OIMH在先进固态照明应用中的潜力.
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