稳定的硫电池在充电过程中通过GeS2和α-S8格子匹配来确保稳定
Xun Jiao1, Xiaoxia Tang1, Jinrui Li1
1The State Key Laboratory of Power Transmission Equipment & System Security and New Technology, Chongqing Key Laboratory of Chemical Process for Clean Energy and Resource Utilization, College of Chemistry and Chemical Engineering, Chongqing University, Chongqing, 400044, China.
Small (Weinheim an der Bergstrasse, Germany)
|July 22, 2023
概括
二硫化物 (GeS2) 通过控制硫种转化和沉积来稳定硫电池 (LSB). 这种材料确保了均的α-S8结晶,防止了接口崩并提高了电池性能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 硫电池 (LSB) 在充电过程中因分子极性降低和体积收缩而遭受多硫化物 (LiPS) 损失和界面崩.
- 这些问题严重阻碍了LSB的周期稳定性和整体业绩.
研究的目的:
- 在充电过程中解决LSB中的LiPS损失和接口崩.
- 通过一种新型材料方法提高LSB的稳定性和电化学性能.
主要方法:
- 使用二硫化物 (GeS2) 与一个 (111) 格子平面匹配α-S8 (113) 格子.
- 通过GeS2.2研究了硫种相互转换和沉积的调节.
- 观察了 LiPSs 在 GeS2 表面的自发吸附,电子增益和转换.
主要成果:
- 在充电过程中,GeS2有效调节硫种的转化和沉积.
- 可溶性LiPS被吸附,获得电子,并在GeS2表面转化为α-S8.
- 在GeS2 (111) 格子平面上实现α-S8的均结晶,保持稳定的阴极-电解质接口.
结论:
- 在LSB中,GeS2作为硫物种的关键调节剂.
- GeS2和α-S8之间的精确格子匹配促进了稳定的接口结构.
- 开发的策略导致了LSBs在充电/放电方面的出色表现.
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