使用多变量分析对和物,芳香物,树脂和青确定剂数据进行青老化的评估
Lorris Bruneau1,2, Séverine Tisse2, Laurent Michon1
1Esso SAF, Avenue Kennedy, F-76330 Port-Jérôme-sur-Seine, France.
ACS omega
|July 24, 2023
概括
青的老化会改变其化学成分,影响性能. 新的分析揭示了芳香物转化为树脂或青的独特途径,表明老化会跳过某些分子分数.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 地质技术工程 地质技术工程
背景情况:
- 青老化是一种物理和化学修饰的过程,显著降低了青的性能.
- 西方研究院开发了SAR-AD (和物,芳香物,树脂,青) 方法,用于详细的青分成.
研究的目的:
- 通过SAR-AD分离方法更详细地研究青老化过程.
- 在老化条件下分析不同青类型和混合物中单个SAR-AD分量的演变.
主要方法:
- 利用SAR-AD方法将老化和未老化的青样本分成八个部分.
- 青样品经过不同时间的压力衰老容器 (PAV) 衰老 (048小时).
- 应用主要组件分析 (PCA) 用于统计分析生成的SAR-AD数据.
主要成果:
- 根据青的组成和老化时间,在SAR-AD分数中观察到各种演变.
- 和物质的影响最小;芳香物质 (特别是芳香物质3) 减少,而树脂和1和2增加.
- PCA确定了两个主要的衰老途径:芳香物2转化为树脂,芳香物3直接转化为青物2.
结论:
- 青老化涉及复杂的分子转变,有不同的途径被确定.
- 在老化过程中,较少极性的分子转化为较多极性的分子,可以绕过中间的SAR-AD分数.
- 青可以直接从芳化合物中形成,而不一定涉及树脂部分.
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