通过绿色和良性亚/超临界流体提取方法从软木和硬木中提取原生木质素
Federica Nardella1, Jens Prothmann2, Margareta Sandahl2
1Department of Chemistry and Industrial Chemistry, University of Pisa Via G. Moruzzi 13 56124 Pisa Italy.
RSC advances
|July 24, 2023
概括
超临界流体提取和CO2膨胀液体提取有效地使用绿色溶剂从木材中分离出有价值的素化合物. 在优化条件下,可以发现大量的宁单体和寡合体,表明轻度宁提取的潜力.
科学领域:
- 生物质价值化和绿色化学.
- 可持续地从纤维素中提取高价值化合物.
背景情况:
- 氨酸是低分子量化合物的丰富来源,但缺乏有效的隔离方法.
- 开发强大的提取技术对于释放红素的潜力至关重要.
研究的目的:
- 调查超临界流体提取 (SFE) 和CO2扩展液体提取 (CXLE) 来从木材中提取木质素.
- 为了评估绿色有机辅溶剂和优化提取参数.
主要方法:
- 用SFE和CXLE作为辅溶剂使用乙醇,乙和乳酸乙烯.
- 利用实验设计方法研究温度,二氧化碳百分比和水含量.
- 使用液体CO2/酸盐/水在60°C,350bar30分钟的温度下进行优化提取.
主要成果:
- 乙烯酸乳酸和乙烯酸产生了最高的可提取性红素重量计量.
- 水含量显著影响了素单体 (LM) 和寡合体 (LO) 的产量;溶剂类型的重要性很小.
- 在优化条件下,从硬木碎片中发现了13个LM和6个红素二次体 (LD).
结论:
- 超临界流体和绿色溶剂为从木材中提取木质素提供了一种温和而有效的方法.
- 该研究强调了通过优化提取工艺来分离有价值的素衍生化合物的潜力.
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