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相关概念视频

Intermolecular Forces03:13

Intermolecular Forces

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Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
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Continuous Charge Distributions01:17

Continuous Charge Distributions

6.9K
Imagine a bucket of water. It contains many molecules, of the order of 1026 molecules. Thus, although it contains discrete elements (molecules) at the microscopic level, macroscopically, it can be considered continuous. Small volume elements of water, infinitesimal compared to the bulk of the bucket's volume, still contain many molecules. Under this framework, quantized matter is approximated as continuous for practical purposes.
The electric charge can also be subjected to an analogical...
6.9K
Van der Waals Interactions01:24

Van der Waals Interactions

64.1K
Atoms and molecules interact with each other through intermolecular forces. These electrostatic forces arise from attractive or repulsive interactions between particles with permanent, partial, or temporary charges. The intermolecular forces between neutral atoms and molecules are ion–dipole, dipole–dipole, and dispersion forces, collectively known as van der Waals forces.
64.1K
Aqueous Solutions and Heats of Hydration02:42

Aqueous Solutions and Heats of Hydration

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Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
14.8K
Potential Due to a Polarized Object01:29

Potential Due to a Polarized Object

438
A neutral atom consists of a positively charged nucleus surrounded by a negatively charged electron cloud. When placed in an external electric field, the external electric force pulls the electrons and nucleus apart, opposite to the intrinsic attraction between the nucleus and the electrons. The opposing forces balance each other with a slight shift between the center of masses of the nucleus and the electron cloud, resulting in a polarized atom. On the other hand, a few molecules, like water,...
438
Energy Associated With a Charge Distribution01:21

Energy Associated With a Charge Distribution

1.6K
The work done to bring a charge through a distance r is given by the potential difference between the initial and the final position. To assemble a collection of point charges, the total work done can be expressed in terms of the product of each pair of charges divided by their separation distance, defined with respect to a suitable origin. Solving this expression gives the energy stored in a point charge distribution.
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相关实验视频

Updated: Jul 22, 2025

Taking Advantage of Reduced Droplet-surface Interaction to Optimize Transport of Bioanalytes in Digital Microfluidics
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水微滴之间的电荷转移取决于它们的大小.

Shiquan Lin1,2, Leo N Y Cao1,2, Zhen Tang1,2

  • 1Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, Beijing 100083, People's Republic of China.

Proceedings of the National Academy of Sciences of the United States of America
|July 24, 2023
PubMed
概括
此摘要是机器生成的。

水微滴中的接触电气化取决于大小. 大滴变为正,小滴变为负,解释了超声波原子化过程中通过电荷转移自发生成过氧化.

关键词:
接触电气化的电气化液体 液体 接口 接口尺寸依赖的大小.水滴是水滴中的水滴.

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科学领域:

  • 物理化学 物理化学
  • 表面科学是一门学科.
  • 电化学 电化学 电化学

背景情况:

  • 接触电化 (CE) 在水中对于化学反应至关重要,包括微滴中自发生成过氧化 (H2O2).
  • 现有的研究主要研究散装水CE,在微米尺寸的水滴中测量和理解CE方面存在挑战.
  • 在水微滴中CE的精确机制仍然模两可.

研究的目的:

  • 提出一种用于量化超声波原子化产生的水微滴中的电荷的新方法.
  • 研究水微滴中接触电气化的机制和尺寸依赖性.
  • 提供支持CE诱导的水中过氧化生成的证据.

主要方法:

  • 开发了一种技术,使用超声波原子化量化水微滴的电荷.
  • 在均电场内观察微滴运动,以计算静电力.
  • 基于实验观察,提出了微滴充电的理论模型.

主要成果:

  • 证明了水微滴CE期间的电荷转移取决于大小.
  • 观察到较大的微粒倾向于获得正电荷,而较小的微粒则获得负电荷.
  • 在超声波原子化过程中,暗示的负电荷从较大的微滴转移到较小的微滴.

结论:

  • 一个理论模型将微滴充电归因于曲率诱导的表面潜力/能量差异.
  • 在相反电荷的分离微滴之间计算的电场足以将氧化离子 (OH-) 转化为基 (OH*).
  • 提供了强有力的证据,证明接触电气化驱动水中微滴中过氧化的自发生成.