相关实验视频
Updated: Jul 22, 2025

Low-energy Cathodoluminescence for OxyNitride Phosphors
Published on: November 15, 2016
对于NIR-II发光的Cr3+-Cr3+聚合物的间隔电荷转移
Shengqiang Liu1, Jingxuan Du1, Zhen Song2
1Beijing Municipal Key Laboratory of New Energy Materials and Technologies, School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing, 100083, China.
这项研究引入了新型近红外II (NIR-II) 宽带发光,来自酸盐矿中的聚合离子 (Cr3+). 这一突破为生物成像,非破坏性测试和夜视应用提供了增强的性能.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 发光光谱光谱法 光光谱法
背景情况:
- 高性能近红外 (NIR) 发光材料对于生物成像和夜视等先进应用至关重要.
- 现有的材料,如化物和分离的离子 (Cr3+),在排放范围和性能上有局限性.
研究的目的:
- 报告第一个基于间隔电荷转移 (IVCT) 的近红外II (NIR-II) 宽带发光在聚合的Cr3+离子中.
- 为了研究Cr3+兴奋剂加拉酸矿的双排放特性和抗热灭行为.
主要方法:
- 合成LaMgGa11O19:0.7Cr3+及其发光性质的表征.
- 对冷吸收光谱,寿命衰变测量和电子磁共振 (EPR) 实验的分析.
- 展示该材料在NIR-II生物成像,非破坏性测试和夜视等方面的应用.
主要成果:
- 在蓝色LED激发下,LaMgGa11O19:0.7Cr3+在NIR-I (890 nm) 和NIR-II (1200 nm) 呈现双发射,其宽度为626 nm的FWHM.
- 由于Cr3+中心之间的能量转移,该材料表现出了显著的反热火行为 (432% @ 290K).
- 这种NIR-II发光归因于Cr3+-Cr3+ → Cr2+-Cr4+ IVCT过渡.
结论:
- 这项工作介绍了通过Cr3+-Cr3+聚合和IVCT进行宽带NIR-II发光的新机制.
- 开发的材料显示了需要NIR-II发射的先进光学应用的巨大潜力.
- 这项研究为设计高性能NIR发光材料开辟了新的途径.
更多相关视频
08:31Luminescence Resonance Energy Transfer to Study Conformational Changes in Membrane Proteins Expressed in Mammalian Cells
Published on: September 16, 2014
08:54Vibrational Spectra of a N719-Chromophore/Titania Interface from Empirical-Potential Molecular-Dynamics Simulation, Solvated by a Room Temperature Ionic Liquid
Published on: January 25, 2020
相关概念视频
¹³C NMR: ¹H–¹³C Decoupling
A broadband decoupling technique is used to simplify these complex, sometimes overlapping, signals. Broadband decoupling relies on a...
Photoluminescence: Applications
Insensitive Nuclei Enhanced by Polarization Transfer (INEPT)
Other Nuclides: 31P, 19F, 15N NMR
While fluorine-19 and phosphorous-31 have high natural abundances (100%) and positive gyromagnetic ratios, nitrogen-15 has a low natural abundance and a negative gyromagnetic ratio. However, nitrogen-15 is still preferred over nitrogen-14 (which has a...