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通过过渡金属单元稳定的异构-基类型的合成和反应性

Lisa Zimmermann¹, Christoph Riesinger¹, Gábor Balázs¹

¹Department of Inorganic Chemistry, University of Regensburg, Universitätsstraße 31, 93053, Regensburg, Germany.

Chemistry (Weinheim an der Bergstrasse, Germany)

|July 26, 2023

概括

这项研究报告了新的过渡金属稳定无机二氧化盐类似物. 这些化合物具有可调节的特性和稳定性,为化学研究提供了一个新的平台.

科学领域:

有机金属化学有机金属化学
无机化学无机化学
材料科学材料科学材料科学

背景情况:

混合二基复合物与电友的反应性尚未得到充分理解.
有机盐是多功能合成中间体,但可能是不稳定的.
开发稳定的无机类似物可以提供新的合成可能性.

研究的目的:

为了合成和表征来自混合二基复合物的新型阴离子化合物.
研究电友性质对这些化合物的结构和动态的影响.
为了探索这些无机diazonium同类物与N-异环碳的反应性.

主要方法:

混合二基复合物的合成及其与14组电友的反应.
谱学表征 (NMR) 和X射线晶体学.
密度功能理论 (DFT) 的计算用于预测反应路径和同位素形成.

主要成果:

合成了一组 [{CpMo(CO) 2}2(μ,η2:2-EPR) ]+ 阴离子化合物库,作为无机二氧化同类物.
电友R的立体和电子性质显著影响P-R键的长度和动态行为.
这些化合物在室温下稳定,与许多有机类型不同.
与N- heterocyclic carbenes (NHCs) 的反应导致未被替代的原子的添加,形成两个异构体.

结论:

过渡金属稳定允许创建强大的无机二氧化类似物.
电友的立体和电子调可以控制化合物特性.
这些新型化合物及其与NHCs的反应在有机金属和无机合成中开辟了新的途径.

关键词:

抗氧化是最重要的.亚是一种.酸盐是什么? 酸盐是什么?合金是一种合金.是一种的物质.

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