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在微氧生物阳极中增强氨氧化
Xiaofang Yan1, Dandan Liu2, Johannes B M Klok3
1Environmental Technology, Wageningen University & Research, P.O. Box 17, 6700 AA Wageningen, The Netherlands.
Environmental science & technology
|July 27, 2023
概括
生物电化学系统 (BES) 有效地转化废水中的. 微氧条件通过形成氧胺显著提高了氧化率,改善了废水处理.
科学领域:
- 环境科学 环境科学
- 电化学 电化学 电化学
- 微生物学 微生物学
背景情况:
- 生物电化学系统 (BES) 提供节能废水处理.
- 除氨的BES的工业应用受到缓慢的速度和途径模糊性的限制.
研究的目的:
- 在不同氧气条件下研究BES中的氨氧化速率和路径.
- 阐明氧胺在微氧和无氧转化中的作用.
主要方法:
- 使用生物电化学系统进行氨转化实验.
- 在受控的微氧 (0.02-0.2 mg-O2/L) 和无氧条件下运行系统.
- 分析了氨氧化率和最终产品的形成.
主要成果:
- 在微氧条件下达到228 ± 0.4 g-N m-3 d-1的氨氧化率,明显高于无氧率 (120 ± 21 g-N m-3 d-1).
- 确定了氧胺 (NH2OH) 作为一个关键的中间体,影响了氨氧化速度限制的阶段.
- 观察到二气作为主要的最终产品,在微氧条件下有75%的效率,在无氧条件下有100%的效率.
结论:
- 微氧条件增强了BES中的氨氧化,主要是通过氧胺的形成.
- 了解这些途径对于推进工业废水处理BES技术至关重要.
- 这项研究提供了关于优化BES性能以有效去除氨的见解.
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