聚 (离子液体) - 金属有机框架衍生的纳米孔碳膜:易于制造和超高面积容量
Yu Shi1, Wenhua Long1, Yue Wang1
1State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai, 201620, China.
Macromolecular rapid communications
|July 28, 2023
概括
研究人员为高性能超级电容器开发了无粘合剂的碳膜. 这些集成电极提供优越的面积容量和能量密度,推进便携式电子.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 便携式和可穿戴设备需要高能量密度的电源.
- 目前的超级电容器面临着面积容量和功率/能量密度的限制.
- 许多电极材料需要粘合剂,使制造复杂化.
研究的目的:
- 为超级电容电极合成无粘合剂,集成的等级石墨多孔碳膜.
- 为了提高移动智能电子设备的超级电容器的面积电容和功率/能量密度.
主要方法:
- 聚离子液体 (PIL) 和金属有机框架 (MOF) 的 Pyrolyzing 复合膜.
- 合成集成的等级图形质多孔碳膜.
- 使用碳化PIL-MOF和PILs衍生的多孔碳膜组装不对称的超级电容器.
主要成果:
- 在一个两电极系统中,实现了9.5 F cm−2的面积电容和1.91 mWh cm−2的能量密度.
- 在全固态超级电容器中证明了面积电容量为3.2 F cm-2和能量密度为0.65 mWh cm-2.
- 超过了大多数先前报告的超级电容电极材料的性能指标.
结论:
- 集成碳膜电极在没有粘合剂的情况下提供高面积电容.
- 这些材料显示出小型化设备和先进的能量存储的巨大潜力.
- PIL的可调性允许在超级电容器中进行更广泛的应用.
相关概念视频
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