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Updated: Jul 21, 2025

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions
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了解在催化C-H键功能化反应中的预催化剂激活和特异化

Jonathan B Eastwood1, L Anders Hammarback1, Thomas J Burden1

  • 1Department of Chemistry, University of York, Heslington, York YO10 5DD, United Kingdom.

Organometallics
|July 28, 2023
PubMed
概括

这项研究揭示了催化C-H功能化最初在前催化剂激活后形成溶剂复合物. 随后的连接物替代是动力学控制的,在达到热力学平衡之前影响产品分布.

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