粗性对可逆的合体凝产量转变的影响
E Nikoumanesh1, R Poling-Skutvik1
1Department of Chemical Engineering, University of Rhode Island, Kingston, Rhode Island 02881, USA.
The Journal of chemical physics
|July 28, 2023
概括
这项研究揭示了使用纤维素纳米晶体凝的厚性热性产量压力流体 (TYSFs) 的基本物理. 一种新的风湿学方法精确地测量了产量压力,并揭示了产量和恢复的机制.
科学领域:
- 材料科学 材料科学 材料科学
- 类风病学 类风病学 类风病学
- 体科学 体科学 体科学
背景情况:
- 粗型产应力流体 (TYSFs) 表现出复杂的行为,取决于切割速率和历史.
- 了解TYSF结构,动力学和风学之间的相互作用至关重要,但具有挑战性.
- 纤维素纳米晶 (CNC) 悬浮物作为具有可调节性质的模型TYSF.
研究的目的:
- 阐明在TYSFs中控制产量和厚性otropic恢复的基本物理.
- 开发一种新型的风湿学协议,用于在TYSF中精确地确定收益率应力.
- 为了确定驱动CNC凝中观察到的质行为的物理化学机制.
主要方法:
- 系统地改变了CNC悬浮的离子强度,以创建模型TYSFs.
- 采用了一种新的风湿学方案:串行爬行分歧.
- 分析了厚性otropic 动力学,并将数据与扩散聚合模型相匹配.
主要成果:
- 确定了一个关键的过渡,准确地确定了产量压力,区分了类似固体和类似流体的制度.
- 证明了克索特洛普动力学崩到一个主曲线上.
- 建立了离子强度,模块和厚性otropic回收率之间的联系.
结论:
- 这项研究确定了关键的物理化学机制,负责在有吸引力的合体凝中产生和提克索特洛普回收.
- 新的串行爬行分歧协议为特征TYSF提供了一个精确的方法.
- 这些发现有助于进一步了解CNC凝等材料中复杂流体行为的基本原理.
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