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在酸性化过程中从经过处理的素菌中再生的纤维
Ronald Gebhardt1, Novin Darvishsefat1
1Chair of Soft Matter Process Engineering (AVT.SMP), RWTH Aachen University, 52062 Aachen, Germany.
Gels (Basel, Switzerland)
|July 28, 2023
概括
在酸性条件下,状素纤维的膨胀不同,转变为酸性凝. 模拟了这种行为,显示胀随着更高的质子度而减少,这是由于减少了素总分子重量.
科学领域:
- 食品科学 食品科学 食品科学
- 材料科学 材料科学 材料科学
- 生物物理学的生物物理.
背景情况:
- 状素纤维是通过挤出到富含的浴中生产的.
- 酸相互作用稳定纤维,但在酸性pH下不那么重要.
- 酸性条件诱导素纤维独特的胀行为.
研究的目的:
- 为了研究在酸性介质中状素纤维的胀行为.
- 了解蛋白纤维内pH依赖的结构转变.
- 模拟胀过程并确定影响胀的关键因素.
主要方法:
- 使用酸纤维在不同度 (pH < 2) 的酸溶液中的胀实验.
- 与水中的胀和1N HCl. 的比较.
- 动力建模合两个二次速率方程来模拟两相膨胀过程.
主要成果:
- 素纤维在酸中表现出双相胀过程,与水中的简单胀不同.
- 在酸中还发生了进一步的胀阶段,这归因于从脂素凝过渡到酸性脂凝.
- 最终的膨胀值随着质子度的增加而下降,遵循缩放关系.
- 这种减少与聚合素结构的分子量减少有关.
结论:
- 状素纤维的稳定性和胀是依赖pH的.
- 酸性条件诱导素凝网络内的结构转变.
- 一个动力模型成功模拟了观察到的膨胀行为,突出了质子度和总分子重量的作用.
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