一个超均的疏水性气体扩散层,用于质子交换膜燃料电池
Yan Xiao1, Xiang Li1, Qianqian Wang2
1Clean Energy Automotive Engineering Center and School of Automotive Studies, Tongji University, Shanghai 201804, China.
ACS applied materials & interfaces
|July 28, 2023
概括
气体扩散层 (GDL) 的新分子疏水处理显著提高了质子交换膜燃料电池的性能. 这种方法减少了电阻,并通过确保均的疏水性来提高功率密度,与传统处理不同.
科学领域:
- 材料科学与工程 材料科学与工程
- 电化学 电化学 电化学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 气体扩散层 (GDL) 是质子交换膜燃料电池 (PEMFC) 中的关键组件.
- 传统的疏水处理,如特,往往导致不均,增加阻力和阻碍性能.
- 优化GDL对于提高燃料电池效率和耐用性至关重要.
研究的目的:
- 通过分子级处理,开发一种均的疏水性GDL.
- 研究修改后的GDL中的质量转移机制.
- 评估均疏水性对PEMFC性能的影响.
主要方法:
- 液相合成为同质分子疏水性GDL制剂.
- 开发一个二维非异热模型来模拟转移机制.
- 燃料电池的实验测试与传统和修改的GDLs.
主要成果:
- 使用分子疏水性GDL,峰值功率密度提高了46%.
- 在1A cm-2时,欧姆电阻和质量传输电阻分别下降了15%和52%.
- 减少了水和 (0.13对0.19),并消除了修改后的GDL中的水友性点,改善了气体流量.
结论:
- 分子级均疏水处理是GDL优化的一个有效策略.
- 这种方法显著降低了PEMFCs的欧姆和质量转移阻力.
- 改进的GDL设计可以提高燃料电池的性能和效率.
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