容易从孔层阶段释放的金属使得在玄武岩碳矿化示范中实现了独特的碳酸盐区分
Nabajit Lahiri1, Quin R S Miller2, Ruoshi Cao2
1Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, Washington 99352, United States.
Environmental science & technology
|July 28, 2023
概括
在玄武岩形成中的地质碳捕集永久存储二氧化碳作为碳酸盐. 结节的化学测绘揭示了对碳矿物化的洞察力,这对于优化未来的二氧化碳封存模型至关重要.
科学领域:
- 地球科学 地球科学 地球科学
- 环境科学 环境科学
- 地质化学 地质化学
背景情况:
- 负碳战略对于减轻温室气体排放至关重要.
- 大陆洪水基岩石中的地质碳捕获提供了永久的二氧化碳储存,以稳定的碳酸盐形式.
- 瓦卢拉基岩碳储存试点项目证明了在实地范围内向哥伦比亚河基岩群 (CRBG) 注入二氧化碳.
研究的目的:
- 分析二氧化碳封存过程中形成的人为碳酸盐的组成和结构.
- 了解碳酸盐沉的机制和cationic物种的作用.
- 提供用于参数化预测模型的数据,用于在反应性储库中对二氧化碳的捕获.
主要方法:
- 微X射线光 (μ-XRF) 化学映射注射后侧墙核心截面.
- 分析碳酸盐结节内的组合区分.
- 在注射前和注射后的侧墙芯和毛孔层水泥的比较.
主要成果:
- μ-XRF映射揭示了碳酸盐结节内的组成区域.
- 人类碳酸盐几乎没有,这表明它具有类似矿的成分.
- 通过深入的化学测绘,揭示了碳矿物化中的阴阳性物种的来源和命运.
结论:
- 在依赖时间的孔液组成下,碳酸盐生长机制得到了阐明.
- 这些发现提供了关键的洞察力,了解玄武岩形成对二氧化碳封存的有效性.
- 结果将使全球二氧化碳封存努力的预测模型的参数化得到改善.
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