新一类高能,高功率电容设备由稳定金属阳极启用
Mahdokht Shaibani1,2,3, Md Joynul Abedin2,3, Meysam Sharifzadeh Mirshekarloo2
1Department of Chemical and Environmental Engineering, RMIT University, Melbourne, Victoria 3001, Australia.
ACS applied materials & interfaces
|July 28, 2023
概括
金属电容器 (LMC) 消除了对前的需求,简化了生产. 这些新设备提供高能量和功率密度,具有长周期寿命,用于先进的能量存储.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 离子电容器 (LIC) 混合了电池和电容技术,以实现高能量/功率密度和寿命.
- 对LICs的一个关键挑战是预化步骤,通常使用金属,这阻碍了大规模采用.
研究的目的:
- 引入一种新的设备类别,金属电容器 (LMC),可以绕过传统LIC的预化要求.
- 为LMC中的金属阳极开发稳定的固体电解质接口 (SEI).
主要方法:
- 在以太基电解质中使用LiNO3和多硫化物开发了一种专门的SEI形成过程.
- 在新的LMC架构中稳定了金属阳极.
- 在硬币和袋细胞水平上测试了设备的性能.
主要成果:
- 优化的硬币电池在30°C下放电时达到55mAhg-1,在8000个周期内保持95%的容量.
- 袋式电池的实际能量密度为13Wh kg-1.
- 该LMC技术成功地消除了前化步骤.
结论:
- 金属电容器代表了一类新的电容储能装置.
- 通过删除预化步骤,LMC为传统LIC提供了一个可扩展和实用的替代方案.
- 稳定的金属阳极为各种阴极化学结构开辟了可能性.
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