物理老化聚合物玻璃的压力扫描体积,虚构压力和记忆效应
Daniele Sonaglioni1, Elpidio Tombari2, G P Johari3
1Physics Department, University of Pisa, Largo Pontecorvo 3, 56127 Pisa, Italy.
The journal of physical chemistry. B
|July 28, 2023
概括
用压力扫描体积计 (PSV) 研究聚合物的物理衰老. 这种技术揭示了老化压力,时间和加压率如何影响聚合物体积和虚拟压力,为结构放松提供了洞察力.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物物理 聚合物物理
- 物理化学 物理化学
背景情况:
- 玻璃中的物理老化减少了体积,和向平衡.
- 玻璃中的结构放松通常被建模为非指数和非线性.
- 差分扫描热量计 (DSC) 分析热歇斯底里热容量 (Cp) 与温度 (T).
研究的目的:
- 用压力扫描体积计 (PSV) 调查聚合物中老化压力 (page),老化时间 (tage) 和加压率对聚合物的老化的影响.
- 在不同的老化条件下分析性聚烯的结构松参数 (β,x,ΔV*).
- 为提供体积 (V) 和虚拟压力 (pf) 在衰老和记忆效应期间变化的定量图表.
主要方法:
- 利用压力扫描体积测量 (PSV) 来研究聚合物化的同热加压和降压.
- 采用已知的非指数和非线性参数 (β,x) 和激活体积 (ΔV*) 用于性聚烯.
- 分析了V和pf随着时间和压力的老化而发生的变化,包括科瓦克斯记忆效应.
主要成果:
- 在PSV扫描中,在压力降低期间显示出一个过渡后的特征,在 - ⋅dV / dp) 超越峰值之前.
- 证明V的单调下降和pf的增加随着tage的增加.
- 给出了各种组合的放松参数 (β,x,ΔV*) 的压力对应的 -{dV/dp) 的通用图.
结论:
- 在研究聚合物中压力诱导的热歇斯底里和结构放松方面,PSV与DSC相似.
- 该研究揭示了PSV扫描期间密度波动响应的显著变化.
- 这些发现对了解玻璃老化和对聚合物加工的技术相关性具有学术意义,可能推动新设备的开发.
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