氧化还原活性物质的重新激活可以提高电化学淡化性能,并将储能合起来
Chenxi Liu1, Xiaotong Li1, Yuan Yao1
1School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150001, China.
Water research
|July 28, 2023
概括
一种新的双重氧化还原策略使用普鲁士蓝色反应器将水性氧化还原流电池 (RFB) 的海水淡化能力提高了100%以上. 这一突破同时提供了高效的淡水生产和能源储存.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 环境工程 环境工程
背景情况:
- 水性氧化还原流电池 (RFB) 是用于同时生产淡水和储能的新兴技术.
- 目前的海水淡化RFB容量受氧化还原活性材料的数量限制,阻碍了实际应用.
研究的目的:
- 为了克服海水淡化RFB的容量限制.
- 为提高海水淡化性能制定一个双重氧化还原策略.
主要方法:
- 使用/铁酸RFB模型进行概念验证.
- 引入普鲁士蓝 (PB) 作为氧化还原活性剂,以实现继电器淡化.
- 淡化能力的性能评估,NaCl去除,能源消耗和电能输出.
主要成果:
- 双重氧化还原策略将海水淡化能力提高了约106.1% (651.2 mAh与理论上的315.9 mAh相比).
- 从34-47毫升海水中获得85%-91%的NaCl去除,盐能耗低 (8.17kJ/mol).
- 该系统提供了显著的电能输出 (55.6-42.5Wh/L),性能优于现有的海水淡化RFB.
结论:
- 双重氧化还原策略有效地重新激活耗尽的材料,使继电器淡化和显著增加容量.
- 这种方法在设计高性能海水淡化RFB方面呈现了范式的转变.
- 这些发现对海水淡化,能源储存和相关领域有广泛的影响.
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