用聚酸硫酸盐对焦废水进行先进处理,以去除有机化合物
Jiangnan Wang1, Fang Chang1, Maosheng Zheng2
1Marine Resources Research Centre, Tianjin Research Institute for Water Transport Engineering, Ministry of Transport, Tianjin 300456, China.
概括
新开发的聚酸硫酸盐 (PASS) 有效地处理了具有挑战性的焦化废水. 这种先进的凝固方法显著降低了化学氧需求 (COD) 和紫外线吸收,提供了一个环保的解决方案.
科学领域:
- 环境化学环境化学
- 水处理技术水处理技术
背景情况:
- 焦化废水由于其高有机强度而带来了重大处理挑战.
- 传统的生物处理方法往往无法满足焦化废水排放标准.
研究的目的:
- 评估新制备的聚酸硫酸盐 (PASS) 对于先进的焦化废水处理的有效性.
- 为了比较PASS性能与已建立的商业凝固剂.
主要方法:
- 使用单因子和塔古奇设计的凝血实验.
- 凝血参数的优化,包括PASS剂量,pH,温度,花速度和时间.
- 分析化学氧气需求 (CODCr) 和UV254吸收率作为关键性能指标.
- 使用紫外线光谱扫描和气体染色体质谱法 (GC-MS) 进行去除有机化合物的表征.
主要成果:
- 在最佳条件下 (7 mmol/L PASS,pH 7,20 °C,75 r/min,30 min) 可降低CODCr从196.67 mg/L降至59.94 mg/L.
- 与铁化物,聚铁硫酸盐,硫酸盐和聚化相比,PASS表现优越.
- 通过臭氧化,活性碳吸附和聚烯胺辅助凝血,通过进一步的治疗增强.
- 凝固有效地去除了高分子量和异环化合物.
结论:
- 新制备的聚酸硫酸盐 (PASS) 是一种高度有效的凝固剂,用于先进的焦化废水处理.
- 通过提供了一个可行的和有效的替代传统方法,以去除耐火有机污染物.
- 该研究为PASS凝血提供了优化的参数,增强了其实际适用性.
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