协调化合物 (2,3,5-Triphenyltetrazolium) 2[CuBr4]作为催化剂,用于固过程的环氧乙烯基结合剂
Alexander E Protsenko1,2, Alexandra N Protsenko1, Olga G Shakirova1
1Department of Chemistry and Chemical Technologies, Komsomolsk-na-Amure State University, 681013 Komsomolsk-on-Amur, Russia.
International journal of molecular sciences
|July 29, 2023
概括
一种新型的铜复合物, (TPhTz) 2[CuBr4],有效地催化了环氧乙烯固化. 这种催化剂提供了更长的反应时间,并保持了聚合物复合材料的材料强度.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 催化剂是一种催化剂.
背景情况:
- 环氧乙烯埃斯特树脂在复合材料中广泛使用.
- 有效的固化催化剂对于控制反应动力学和材料特性至关重要.
- 八酸盐 (CoOct) 是一种常见的,但有时有限的固化加速器.
研究的目的:
- 为了合成和描述一个新的铜复合体, (TPhTz) 2[CuBr4].
- 为了评估这个复合物的催化活性在环氧乙烯基固化.
- 将其性能与标准的基催化剂进行比较,并评估其对复合材料性能的影响.
主要方法:
- 铜复合体 (TPhTz) 2[CuBr4]的合成和光谱表征.
- 在环氧乙烯基固化中对催化性能的评估,与八酸 (CoOct) 相比.
- 测量激活能量和评估玻璃纤维增强塑料的屈曲强度和硬度.
主要成果:
- 铜复合物 (TPhTz) 2[CuBr4]在环氧乙烯固化过程中表现出催化活性.
- 它的激活能量为54.7kJ/mol,高于Co(Oct) 2,表明该过程速度较慢,但可能更容易控制.
- 增加复合物并没有损害由玻璃纤维增强的塑料复合材料所产生的屈曲强度或硬度.
结论:
- 复合铜 (TPhTz) 2[CuBr4] 作为一个有效的固化加速器,用于环氧乙烯基系统.
- 它的使用可以延长加工时间,有利于诸如真空辅助树脂转移成型等技术.
- 催化剂可以在不损害机械完整性的情况下生产高性能聚合物复合材料.
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