刚性聚氨泡作为来自新型上酸基聚合物的热绝缘材料
Aiga Ivdre1, Arnis Abolins1, Nikita Volkovs2
1Latvian State Institute of Wood Chemistry, 27 Dzerbenes St., LV-1006 Riga, Latvia.
Polymers
|July 29, 2023
概括
这项研究探讨了使用树皮衍生的亚酸 (SA) 来制造生物基聚合物,用于刚性聚氨 (PUR) 泡. 这些新的基于SA的PUR泡显示出作为具有竞争力的隔热材料的前景.
科学领域:
- 生物质价值化 生物质价值化
- 聚合物化学 聚合物化学
- 可持续的材料 可持续的材料
背景情况:
- 石油基聚合物广泛用于聚氨 (PUR) 生产.
- 从生物质中开发生物基替代品支持循环经济.
- 树树皮为新的聚合物合成提供了潜酸 (SA) 的潜在来源.
研究的目的:
- 确定基于酸的新型聚醇的最佳合成路径.
- 使用这些SA基聚合物生产刚性PUR泡.
- 评估基于SA的PUR泡作为隔热的性能和潜力.
主要方法:
- 通过与各种酒精脱聚合SA的化合成新型聚醇.
- 通过测试水分含量,基/酸值和粘度来表征聚醇.
- 准备并评估了刚性PUR泡,将其性能与商业材料进行比较.
主要成果:
- 成功合成了基于SA的聚醇和制备了固的PUR泡,含有约20%重量%的可再生能源.
- 基于SA的PUR泡表现出具有竞争力的特性:表面密度 (~33kg/m3),高封闭细胞含量 (~94%),压缩强度 (0.25MPa) 和低导热率 (~0.019W/m·K)).
结论:
- 基于SA的聚醇可用于生产刚性PUR泡.
- 这些生物基泡显示出作为有效的隔热材料的巨大潜力.
- 这项研究为聚氨行业的可持续替代品做出了贡献.
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