凝凝结-自发漂浮综合工艺在水处理中的设计和应用:"水中的云"
Jianguo Zhang1, Yan Yan1, Wenlin Jia1
1School of Chemistry and Materials Science, Jiangsu Normal University, Xuzhou 221116, China.
Water research
|July 29, 2023
概括
新的凝凝结-自发漂浮 (GCSF) 过程使用溶解的气体来有效地处理地表水. 这种方法提供了稳定的性能和较短的周期,与传统的溶化空气漂浮相比,达到80-95%的污染物去除.
科学领域:
- 环境工程 环境工程
- 水处理技术水处理技术
- 材料科学 材料科学 材料科学
背景情况:
- 传统的凝结溶解空气漂浮方法在效率和运行稳定性方面存在局限性.
- 自发漂浮过程通过利用固有的溶解气体为水处理提供了潜在的替代方案.
研究的目的:
- 研究表面水处理的凝凝结-自发漂浮 (GCSF) 过程的有效性和机制.
- 优化GCSF的操作参数,并评估其环境安全.
主要方法:
- 系统地将GCSF工艺应用于地表水.
- 优化甲基酸盐 (SA) 与硫酸盐 (AS) 的剂量比和添加序列.
- 分析不同pH值的净化效率.
- 密度函数理论 (DFT) 计算以阐明吸附机制.
主要成果:
- 最佳的SA:AS比率为1.5:1-2.5:1,在AS之前增加了15-120个SA.
- 通过稳定的凝流形成和溶解气体封装实现了80% - 95%的污染物去除.
- 由于增强的聚合物疏水性,净化效率与pH 4-9正相关.
- 剩余SA和的度分别低于1 mg/L和0.05 mg/L,确保生态安全.
结论:
- GCSF提供了一种稳定高效的表面水处理方法,性能优于传统的溶化空气漂浮.
- 该过程的机制涉及交叉连接的花通过溶解氧的协同吸附,由pH依赖的疏水性驱动.
- GCSF以低残留污染物水平证明了生态安全.
相关概念视频
Coagulation
331
Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
331
Colloidal precipitates
622
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
622
Factors Affecting Solubility
33.5K
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of the ionic compound). This is an example of a phenomenon known as the common ion effect, which is a consequence of the law of mass action that may be explained using Le Chȃtelier’s principle. Consider the dissolution of silver iodide:
33.5K
Centrifugation
2.3K
Centrifugation is a separation technique based on differences in density or size. It is commonly used to separate solids from aqueous interferents. During centrifugation, the sample is placed in centrifugation tubes and spun at high angular velocity, which allows centrifugal force to act differentially on the different densities or masses of the components. After spinning, the supernatant liquid is decanted. Depending on the specific application, either the pellet or the supernatant is retained...
2.3K


