酸盐和铁铁的协同作用,以提高藻类载荷水处理中的超过性能
Yonghui Han1, Jinlong Wang1, Daliang Xu1
1National Engineering Research Centre for Bioenergy, Harbin Institute of Technology, Harbin 150090, China; State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, China.
Water research
|July 30, 2023
概括
酸盐/FeSO4的预处理显著减少了超过 (UF) 中藻类引起的膜污染. 这种方法增强了藻类聚合和有机物去除,改善了 UF 的性能和流量.
科学领域:
- 环境科学 环境科学
- 水处理技术 水处理技术
- 材料科学 材料科学 材料科学
背景情况:
- 超过 (UF) 由于严重的膜污染,在处理含有藻类的水中面临着挑战.
- 藻类污染物显著阻碍了UF的效率和运行寿命.
研究的目的:
- 调查酸盐/FeSO4 (Fe(VI) /Fe(II)) 预处理对在UF中减轻藻类引起的膜污染的有效性.
- 为了提高性能和减少处理藻类污染水的UF系统中的污染.
主要方法:
- 在UF之前使用了酸盐/FeSO4 (Fe(VI) /Fe(II)) 预处理策略.
- 分析了泽塔电位,粒子大小,溶解有机碳 (DOC),UV254,K+和光谱的变化.
- 评估的分子重量分布和膜接口特征.
- 应用扩展的德贾古因-兰多-维维-奥弗比克 (XDLVO) 理论用于机制分析.
主要成果:
- Fe (VI) /Fe (II) 预处理增强了藻类聚合,并通过in-situ Fe (III) 生产增加了花大小.
- 与单独使用Fe (VI) 相比,减少了细胞内有机物 (IOM) 的产生和小分子有机物的形成.
- 显著减轻藻源污染,使终端膜流量从0.16增加到0.62 (L/m2/h).
- 可逆和不可逆的污染分别减少了67.1%和64.1%.
- 通过延迟蛋糕过和削弱疏水吸附,改变了污染机制.
结论:
- Fe (VI) /Fe (II) 预处理通过减少藻类引起的膜污染,有效地提高了UF的性能.
- 这一策略为处理含有藻类的水和延长膜寿命提供了一个有希望的方法.
- 铁VI) 和铁II) 的协同作用优化了有机物去除和污染缓解.
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