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Atomic Emission Spectroscopy: Overview01:20

Atomic Emission Spectroscopy: Overview

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Atomic emission spectroscopy (AES) is an analytical technique used to determine the elemental composition of a sample by analyzing the light emitted from excited atoms. In AES, atoms in a sample are excited to higher energy levels by thermal energy from high-temperature sources, such as plasma, arcs, or sparks. When these excited atoms return to lower energy states, they emit light at specific wavelengths characteristic of each element. The resulting atomic emission spectrum, which consists of...
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Atomic Emission Spectroscopy: Lab01:29

Atomic Emission Spectroscopy: Lab

198
AES is a powerful analytical technique, especially effective when used with plasma sources, producing abundant spectra in characteristic emission lines. The Inductively Coupled Plasma (ICP), in particular, yields superior quantitative analytical data due to its high stability, low noise, low background, and minimal interferences under optimal experimental conditions. However, newer air-operated microwave sources are emerging as promising alternatives that could be more cost-effective than...
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相关实验视频

Updated: Jul 20, 2025

Expression of Cementitious Pore Solution and the Analysis of Its Chemical Composition and Resistivity Using X-ray Fluorescence
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Expression of Cementitious Pore Solution and the Analysis of Its Chemical Composition and Resistivity Using X-ray Fluorescence

Published on: September 23, 2018

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使用便携式X射线光单元的元素量化模型.

Claudio H González-Rojas1, Cristián Castro-Rodriguez1, Sebastián Gutiérrez-Vivanco1

  • 1Department of Chemistry, Faculty of Sciences, Universidad de Tarapacá, Velásquez Av. 1775, XV Region, Box 7-D, Arica, Chile.

MethodsX
|July 31, 2023
PubMed
概括

一种新方法有效地使用便携式X射线光 (pXRF) 来量化土壤. 这种方法与原子吸收光谱学 (AAS) 验证,为沉积物分析提供了可靠的协议.

关键词:
是一种的定量分析确定性的决定这是一款便携式的便携式手机.在量化方面,它是有数量的.一个X射线的光效应.

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科学领域:

  • 环境科学 环境科学
  • 分析化学 分析化学
  • 地质化学 地质化学

背景情况:

  • 准确量化土壤元素对于环境监测和农业应用至关重要.
  • 便携式X射线光 (pXRF) 为元素分析提供了可在现场部署的解决方案.
  • 现有的pXRF方法在准确确定分析物度方面可能会带来挑战,特别是对于等元素.

研究的目的:

  • 开发和验证一种可靠的方法来量化土壤样本中的,使用便携式X射线光 (pXRF).
  • 将pXRF结果与标准分析技术 - - 原子吸收光谱 (AAS) 进行比较.
  • 为了解决pXRF数据解释的局限性,以获得准确的重量/重量 (w/w) 分析物百分比.

主要方法:

  • 使用重力测量技术与和酸制备理想矩阵.
  • 使用标准参考材料 (骨灰) 校准的光排放线.
  • 在理想样本上使用线性相关性和统计推理对pXRF与AAS的验证.

主要成果:

  • 与AAS标准曲线 (值为1.8和1.68) 相比,pXRF对理想样本中的的量化始终高估了度.
  • 观察到高相关系数 (接近1.0),表明pXRF和AAS之间存在可预测的关系.
  • 开发的统计推理方程允许对pXRF过高估计进行校正.

结论:

  • 拟议的pXRF方法,加上统计校正,为量化土壤和沉积物样本中的提供了有效的手段.
  • 本协议解决了与AAS相比pXRF的高估趋势.
  • 该研究验证了pXRF在环境矩阵中可靠的元素分析的应用.