稳定和低值的光子上升转换在有机晶体的非脱气水中
Yoichi Murakami1, Riku Enomoto1
1Laboratory for Zero-Carbon Energy, Institute of Innovative Research, Tokyo Institute of Technology, Meguro, Tokyo, Japan.
Frontiers in chemistry
|July 31, 2023
概括
研究人员开发了稳定的固态有机晶体,用于光子上转换 (UC). 这些晶体能够在水中有效地发出蓝色UC辐射,为新型光子在诊断和治疗中的应用铺平了道路.
科学领域:
- 光子学是指光子学的使用方法.
- 材料科学 材料科学 材料科学
- 有机化学 有机化学
背景情况:
- 光子上转换 (UC) 将低能光子转换为高能光子,使新的光子应用成为可能.
- 基于三倍三倍灭绝 (TTA) 的UC在低强度光线中是有效的,但通常在液体溶液中进行研究.
- 开发稳定,固态的UC材料对于更广泛的应用至关重要.
研究的目的:
- 在固态格式中开发和描述高性能,空气稳定的分子UC晶体.
- 为了研究在水性环境中使用这些固态UC晶体的可行性.
- 评估水中的晶体的性能,包括排放,稳定性和激发要求.
主要方法:
- 在稳定的固体溶液阶段制造双组分有机晶体.
- 在绿黄色光激发 (542 nm) 时蓝色UC辐射的表征.
- 评估激发强度的依赖性,时间稳定性和水中的光照射耐用性.
主要成果:
- 开发了稳定在空气中的高性能分子UC晶体.
- 在542nm激发后,在水环境中实现了蓝色UC发射.
- 在非脱气水中,经过证明的低激发值强度 (mW/cm2) 和高耐用性 (>40小时).
结论:
- 开发的分子固体溶液UC晶体在水性条件下是可行的.
- 这些晶体为水中基于UC的光子应用提供了一个有前途的平台.
- 潜在的应用包括体内诊断,临床和治疗用途.
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