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Updated: Jun 8, 2026

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局部的表面等离子体共振诱导合作Jahn-Teller效应用于晶体相变的纳米晶体

Masanori Sakamoto1, Masaki Hada2, Wataru Ota3,4

  • 1Institute for Chemical Research, Kyoto University, Uji, Kyoto, 611-0011, Japan. sakamoto@scl.kyoto-u.ac.jp.

Nature communications
|July 31, 2023
PubMed
概括

局部表面等离子体共振 (LSPR) 诱导了CuS纳米晶体中的Jahn-Teller效应,导致离子运动延迟了LSPR放松,并使红外传感器的光切换导电性成为可能.

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相关概念视频

Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...