通过有害的富含铁的废渣渣来可控制备高性能安德拉基玻璃陶的研究
Xiaomin Liu1, Yufeng Wu1, De'an Pan1
1Institute of Circular Economy, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing 100124, PR China.
The Science of the total environment
|August 1, 2023
概括
/化渣 (LSS-ZSS) 可以转化为高性能玻璃陶,固定重金属. 这项研究解决了LSS-ZSS中铁氧化物所带来的挑战,以有效利用资源.
科学领域:
- 材料科学 材料科学 材料科学
- 废物管理 废物管理
- 地质化学 地质化学
背景情况:
- /化渣 (LSS-ZSS) 由于历史高储量和重金属含量,存在处置挑战.
- 在LSS-ZSS中,氧化铁 (FeOx) 可能会导致处理问题,如溢和过早结晶.
- 在玻璃陶中使用LSS-ZSS为废物积累和重金属固化提供了解决方案.
研究的目的:
- 从LSS-ZSS开发高性能玻璃陶.
- 为了克服与LSS-ZSS中高FeOx含量相关的技术挑战.
- 研究LSS-ZSS转化为玻璃陶的过程中的结构性质关系.
主要方法:
- 对LSS-ZSS进行方向修改.
- 结晶运动的调节.
- 使用扫描电子显微镜 (SEM),粉末X射线衍射 (PXRD),里埃变换红外光谱 (FTIR) 和X射线光电子光谱 (XPS) 的表征.
主要成果:
- 成功制备玻璃陶,使用安德拉和血作为主要晶体相.
- 系统地研究了形态学,相变,细结构和铁的价值状态.
- 基本眼镜的最大收缩率为27%.
- 获得的最大屈曲强度为128 MPa,玻璃陶的压力强度为890 MPa.
结论:
- 从富含铁的LSS-ZSS开发了一种生产高性能玻璃陶的方法.
- 在玻璃陶矩阵内证明了重金属的有效固化.
- 提供了对铁成分行为和相位演变的见解.
- 突出了有害的LSS-ZSS和磁场应用的资源利用潜力.
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