使用印技术对粉末样本进行定量分析,作为LA-ICP-MS的样本准备方法
Masahiro Kobayashi1, Hiromasa Namiki2, Hideo Hayashi2
1Tokyo Metropolitan Industrial Technology Research Institute, 2-4-10 Aomi, Koto-ku, Tokyo, 135-0064, Japan. kobayashi.masahiro@iri-tokyo.jp.
概括
这项研究引入了一种新的丝网印刷方法,用于准备激光除的均质样本,用于诱导合等离子体质谱法 (LA-ICP-MS). 这种技术可以实现准确的定量分析,而不需要矩阵匹配标准.
科学领域:
- 分析化学 分析化学
- 材料科学 材料科学 材料科学
背景情况:
- 激光除感应合等离子体质谱法 (LA-ICP-MS) 是一种直接的固体样本分析技术.
- 定量LA-ICP-MS受阻于对矩阵匹配标准的需求.
研究的目的:
- 开发一种用于定量LA-ICP-MS的多功能样品制备方法.
- 在LA-ICP-MS分析中克服矩阵匹配标准的局限性.
主要方法:
- 开发了一种新的丝网印刷技术,用粉末制备类似片的样本.
- 样品粉末分散在液体树脂中,加上内部标准,并均质化.
- 通过控制分析物度与内部标准对比,实现了内部标准化.
主要成果:
- 由于试剂的液态性质,很容易获得均的样本.
- 在不依赖于矩阵匹配标准的情况下,可以实现准确的定量分析.
- 该方法通过分析TiO2粉中的杂质元素来验证.
结论:
- 开发的丝网印刷方法为定量LA-ICP-MS提供了一种灵活和多用途的方法.
- 这种技术通过消除对特定矩阵匹配标准的需求,显著扩大了LA-ICP-MS的适用性.
- 使用这种创新的样本准备技术分析各种材料的潜力.
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