通过周期分子链传输光学声子传输中的最大传播速度和切伦科夫效应
Alexander L Burin1, Igor V Parshin1, Igor V Rubtsov1
1Department of Chemistry, Tulane University, New Orleans, Louisiana 70118, USA.
The Journal of chemical physics
|August 2, 2023
概括
光学声子在聚合物中有效地传输能量. 当光学声波速率超过声学声波速率时,它们的弹道运输是保持的,防止脱凝和能量损失.
科学领域:
- 凝聚物质物理学 凝聚物质物理学
- 材料科学是一种材料科学.
- 聚合物科学 聚合物科学
背景情况:
- 光学声子是高分子中高效的能量载体,因为它们具有移位和高组速度.
- 无声的相互作用,特别是与声学声子的相互作用,会导致脱节,并限制长距离的弹道运输.
研究的目的:
- 研究光学和声学声子相对速度对聚合物中光学声子传输的脱凝性的影响.
- 为了确定光学声子弹道运输被保留或抑制的条件.
主要方法:
- 基于能量和动量保存原理的理论分析,用于声子吸收和发射.
- 对光学声波器寿命的数值评估.
主要成果:
- 当光学声的集体速度小于声学声的声速时,光学声传输的脱合性被显著抑制.
- 相反,当光学声波的速度超过声波的速度时,弹道运输被切伦科夫式的声波声波辐射大大抑制.
结论:
- 光学和声学声子的相对速度对于确定聚合物中的弹道运输的性质和程度至关重要.
- 了解这些速度动态对于控制聚合物材料中的能量传输至关重要.
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