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相关概念视频

Colors and Magnetism03:02

Colors and Magnetism

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Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
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Ferromagnetism

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Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
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Oxidation of Alkenes: Syn Dihydroxylation with Potassium Permanganate02:21

Oxidation of Alkenes: Syn Dihydroxylation with Potassium Permanganate

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Alkenes can be dihydroxylated using potassium permanganate.  The method encompasses the reaction of an alkene with a cold, dilute solution of potassium permanganate under basic conditions to form a cis-diol along with a brown precipitate of manganese dioxide.
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In the presence of oxidizing agents, phenols are oxidized to quinones. Quinones can be easily reduced back to phenols using mild reducing agents. The electron-donating hydroxyl group enhances the reactivity of the aromatic ring, enabling oxidation of the ring even in the absence of an α hydrogen.
o-hydroxy phenols are oxidized to o-quinones and p-hydroxy phenols to p-quinones. Such redox reactions involve the transfer of two electrons and two protons. The reversible redox...
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Alkenes are converted to 1,2-diols or glycols through a process called dihydroxylation. It involves the addition of two hydroxyl groups across the double bond with two different stereochemical approaches, namely anti and syn. Dihydroxylation using osmium tetroxide progresses with syn stereochemistry.
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Synthetic Methodology for Asymmetric Ferrocene Derived Bio-conjugate Systems via Solid Phase Resin-based Methodology
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带有氧化铁的磁性诱导二元铁素

Saif Ullah1, Stephanie Jensen1, Yanyao Liu2

  • 1Department of Physics and Center for Functional Materials, Wake Forest University, Winston-Salem, North Carolina 27109, United States.

Journal of the American Chemical Society
|August 2, 2023
PubMed
概括
此摘要是机器生成的。

通过使用金属有机框架主体来实现化学氧化铁. 这使得一种新型的高旋转Fe (II) 状态能够迅速结合并释放氧气,从而改变其电子和磁性结构.

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科学领域:

  • 有机金属化学
  • 材料科学
  • 磁化学

背景情况:

  • 铁素的结构和电子特性在70多年内基本保持不变.
  • 之前通过直接结合铁对铁的化学氧化试验没有成功.
  • 之前没有报告氧化铁素的显著结构或磁性变化.

研究的目的:

  • 基本上改变了铁素的电子和磁性结构.
  • 通过修改其宿主环境来实现铁素的化学氧化.
  • 研究氧与铁素的可逆结合.

主要方法:

  • 使用金属有机框架 (MOF) 作为铁素的宿主材料.
  • 使用一套光谱和分析技术,包括Mößbauer光谱,EXAFS,现场IR,SQUID,TGA和EDXRF.
  • 进行初始建模以补充实验数据.

主要成果:

  • 在MOF中观察到一种新的,物理拉伸/曲的高旋转Fe (II) 状态.
  • 这种高旋转的Fe (II) 状态很容易从空气中接受氧气,导致氧化到Fe (III).
  • 使用温度波动实验证明氧结合是可逆的.

结论:

  • 这种金属-有机框架封装能够对铁素的电子和磁性进行前所未有的控制.
  • 在铁素中实现了可逆的氧结合和氧化状态变化.
  • 这项工作为对有机金属分子进行传感或催化应用开辟了新的途径.