通过铁和增强的长期有机碳保存
Oliver W Moore1, Lisa Curti2, Clare Woulds3
1School of Earth and Environment, University of Leeds, Leeds, UK. o.moore@leeds.ac.uk.
Nature
|August 2, 2023
概括
铁和催化了梅拉德反应,在海洋环境中增强了沉积物有机碳的保存. 这一过程对全球碳循环和地质时间表产生了重大影响.
科学领域:
- 地质化学
- 海洋科学
- 有机地化学
背景情况:
- 沉积物有机碳 (OC) 的保存对全球碳和氧气循环至关重要.
- 驱动海洋沉积物OC保存的机制尚未完全理解.
- 梅拉德反应可以地质聚合有机分子,但在海洋温度下它的速度很慢.
研究的目的:
- 研究铁和在海洋沉积物温度下催化梅拉德反应的作用.
- 量化这种催化反应对海洋沉积物OC保存的贡献.
- 评估铁和在地质时间的全球OC保存的影响.
主要方法:
- 研究梅拉德反应动力学的化实验.
- 对反应产物的化学特征进行分析.
- 孔水建模以估计OC的保存率.
主要成果:
- 铁和离子和矿物质在相关温度下非生物催化梅拉德反应.
- 反应产品的化学特征与大陆边缘沉积物中的溶解和总OC相匹配.
- 通过这种途径在海洋沉积物中估计有4.1 Tg C yr-1.
结论:
- 铁和催化梅拉德反应显著增强海洋沉积物中的OC保存.
- 这种非生物过程对全球沉积有机碳的埋葬有很大贡献.
- 海洋铁和输入的变化可能对长期全球OC保存产生重大,尚未探索的影响.
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