调节结合块共聚物的序列结构使大面积单元有机太阳能电池具有高效率和稳定性
Yujun Cheng1, Qilong Mao1, Chunxiang Zhou1
1College of Chemistry and Chemical Engineering/Institute of Polymers and Energy Chemistry (IPEC), Nanchang University, 999 Xuefu Avenue, Nanchang, 330031, China.
研究人员使用结合块共聚合物 (CBC) 开发了新的单元有机太阳能电池 (SCOSC). 对CBC序列长度和规律性的精确控制显著提高了设备的效率和稳定性,实现了创纪录的13.4%效率.
科学领域:
- 材料科学 材料科学 材料科学
- 有机电子 有机电子
- 聚合物化学 聚合物化学
背景情况:
- 单组件有机太阳能电池 (SCOSCs) 提供了有前途的形态和稳定性.
- 了解合块共聚合物 (CBC) 序列结构对自组装和设备性能的影响至关重要,但有限.
- 开发高效稳定的SCOSC需要精确控制聚合物块排列.
研究的目的:
- 研究CBC的序列长度和分布规律性对自我组装,膜形态和设备性能的影响.
- 用量身定制的序列结构合成和表征新的CBC.
- 通过使用优化的CBC来演示大面积刚性/灵活性SCOSC的制造.
主要方法:
- 使用双和单聚合方法合成一系列CBC (D18(20) -b-PYIT,D18(40) -b-PYIT,D18(60) -b-PYIT,D18(40) -b-PYIT) 的合成.
- 描述CBC自组装,膜形态和光电子特性.
- SCOSC器件的制造和性能测试,包括大面积叶片涂层的刚性/柔性电池.
主要成果:
- 精确操纵CBC序列长度和规律性,微调自组装,优化膜形态和改进的光电子特性.
- 观察到能耗减少,同时提高效率和稳定性.
- 基于D18(40)-b-PYIT的装置实现了13.4%的高效率,增强了稳定性.
- 正规的序列分布和合适的长度促进了印刷设备的容易薄膜形成.
- 首次展示了带叶片涂层的大面积刚性/灵活性SCOSC,其效率分别为11.62%和10.73%.
结论:
- CBCs的序列结构显著影响SCOSC的性能.
- 定制序列长度和规律性是优化SCOSC效率和稳定的可行策略.
- 开发的CBC能够高效地大面积制造具有高性能的刚性/灵活性SCOSC.
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