电透析对体几何和动态的影响:为什么我的膜堆即使经过精细的预处理也被堵塞了?
Wenjing Lu1, Yuchen Du2, Rongqiang Fu3
1College of Environment and Safety Engineering, Qingdao University of Science and Technology, Qingdao 266042, Shandong, China.
The Science of the total environment
|August 4, 2023
概括
电透析 (ED) 堵塞是由合物聚合引起的,特别是在高盐度下. 应用的电场和pH值显著增加了合体大小,导致间隔器堵塞.
科学领域:
- 环境科学 环境科学
- 化学工程是化学工程的重要组成部分.
- 材料科学 材料科学 材料科学
背景情况:
- 电透析 (ED) 是一种用于海水淡化的膜工艺.
- 在ED中间隔器堵塞是一个持久的问题,通常归因于合体污垢.
- 在ED中,合体行为和堵塞的确切机制尚不清楚.
研究的目的:
- 为了研究ED参数对合体几何和动态的影响.
- 为了阐明合物诱导的ED堵塞的原因和机制.
- 为了确定盐度,电流密度和pH对合体聚合的作用.
主要方法:
- 电透析用于治疗状盐溶液.
- 该研究分析了层状流,盐度,电流密度和pH的影响.
- 在淡化过程中测量了体的大小,几何形状和动态.
主要成果:
- 应用电场显著增加了合体颗粒大小 (高达54.52倍).
- 盐度升高 (0.1至1mol/L NaCl) 导致颗粒大小激增149倍,形成.
- 低电流密度促进了小BSA颗粒的聚合,而酸性pH诱导了形状变化和尺寸膨胀.
结论:
- 在较高盐度 (>1mol/L) 时,结合体聚合被证实是ED中间隙堵塞的原因.
- ED参数,特别是电场和盐度,极大地影响着合体的行为和污染.
- 了解这些机制可以改进ED的操作策略和减少膜污染.
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