关于MIBC-PEG混合表面活性剂对泡稳定性的强化机制的研究
Mengdi Xu1, Fangyu Guo2, Xicheng Bao2
1Chinese National Engineering Research Center of Coal Preparation and Purification, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China.
ACS omega
|August 7, 2023
概括
将聚乙烯甘醇-1000 (PEG) 添加到甲基异布基 (MIBC) 泡中,可以显著提高细煤漂浮泡的稳定性. 这种混合表面活性剂系统通过协同效应增强了气泡凝聚抑制和液膜稳定性.
科学领域:
- 表面化学 表面化学
- 材料科学 是一种材料科学.
- 化学工程是化学工程的组成部分.
背景情况:
- 泡是漂浮中的关键表面活性剂,减少表面张力和稳定泡.
- 非离子混合表面活性剂通常用于细煤漂浮.
研究的目的:
- 为了研究一种混合表面活性剂系统的泡特性,该系统由甲基异布碳醇 (MIBC) 和聚乙烯甘醇-1000 (PEG) 组成.
- 了解MIBC-PEG在宏观和微观尺度上的泡特性上的协同效应.
主要方法:
- 测量表面张力 测量表面张力
- 动态泡稳定性分析
- 泡形态观察 泡形态观察
- 泡膜排水量测量 泡膜排水量测量
主要成果:
- 聚乙烯甘醇-1000 (PEG) 显示出比甲基异布基醇 (MIBC) 更高的表面活性,在组合时显著降低了溶液表面张力.
- 将PEG添加到MIBC中显著提高了泡稳定性和减少了泡大小,将分布转移到一个单一的峰值.
- 液体薄膜的排水速度减慢,由于MIBC和PEG在气液界面的协同吸附,薄膜的稳定性得到改善.
结论:
- 由表面张力梯度和增强的马兰戈尼流动驱动的MIBC和PEG之间的协同效应,改善了液膜稳定性和自我愈合.
- 这种混合表面活性剂系统提供了优越的泡性能,用于细煤漂浮,而不是单一的泡.
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