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原子分散铁双功能氧气电催化剂的双封闭结构,用于高性能空气电池
Xue Zhao1, Mengshan Chen2, Zenghui Bi3
1Faculty of chemistry and chemical engineering, Yunnan Normal University, Kunming, 650500, China.
Small (Weinheim an der Bergstrasse, Germany)
|August 7, 2023
概括
研究人员开发了一种新的双功能氧气电催化剂 (FeBCN/NHCS),用于可充电的空气电池 (ZAB). 这种催化剂在氧降解反应 (ORR) 和氧演化反应 (OER) 两方面都表现出卓越的性能,使耐用和高功率的ZABs成为可能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 纳米技术纳米技术
背景情况:
- 可充电的空气电池 (ZAB) 需要高效的双功能电催化剂,以减少氧气 (ORR) 和氧气演变 (OER).
- 现有的催化剂往往难以同时实现两种反应的高活性和耐用性.
研究的目的:
- 开发一种新的双功能氧气电催化剂,以提高ZAB的性能.
- 为了研究新催化剂的结构-活性关系.
主要方法:
- 在SiO2微球上合成金属--集群-有机-聚合物 (FeBCN/NHCS),使用1,10-类复合和空间限制.
- 使用电化学技术评估ORR和OER的电催化活性.
- 用FeBCN/NHCS作为空气阴极组装的ZAB,以评估性能和耐用性.
主要成果:
- FeBCN/NHCS催化剂的ORR半波潜力为0.893V与RHE,超过了Pt/C.
- 实现了361mV的低OER超电位 (η10).
- 在ZAB中证明了高功率密度,特定容量和出色的充放电耐用性.
结论:
- FeBCN/NHCS催化剂具有高表面积,单原子Fe和B兴奋剂,是一种高效的双功能氧气电催化剂.
- 这项工作为ZAB提供了有希望的催化剂,并为设计先进的氧气电催化剂提供了洞察力.
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