森林火灾的化学标记物 - - 排水表面分析 通过LC/Q-TOF-MS对水进行分析
Imma Ferrer1, E Michael Thurman1
1Department of Civil, Environmental, and Architectural Engineering, University of Colorado Boulder, CO 80309, USA.
Chemosphere
|August 7, 2023
概括
野火有机化合物在地表水中使用高分辨率质谱学识别. 这些化合物,包括多碳酸,作为野火事件的有效化学标记物.
科学领域:
- 环境化学环境化学
- 分析化学 分析化学
- 质谱测量质量谱测量
背景情况:
- 野火会将许多有机化合物释放到环境中.
- 地表水可能被野火副产品污染.
- 准确识别这些化合物对于环境监测至关重要.
研究的目的:
- 开发一种定量方法,用于在地表水中识别野火产生的有机化合物.
- 为了验证特定化合物的方法的准确性和精度.
- 将该方法应用于受野火影响的现实世界样本.
主要方法:
- 固体相提取 (SPE) 用于样品制备.
- 液体染色学-四极飞行时间质谱学 (LC/Q-TOF-MS) 检测.
- 使用准确的目标化合物的质量和碎片离子进行识别.
主要成果:
- 为14种目标化合物 (例如,胺,,,双聚碳酸和双聚碳酸) 开发并验证了一种方法.
- 该方法实现了>95%的准确性和3-10%的精度.
- 在科罗拉多州的野火排水中检测到高达59.5μg/L的度,总计约200μg/L.
- 非目标分析揭示了额外的聚碳酸异构体.
结论:
- 开发的LC/Q-TOF-MS方法对于在地表水中识别野火衍生的有机化合物是有效的.
- 这些化合物存在于高度,可以作为野火事件的可靠化学标记物.
- 该研究强调了野火影响水域中其他相关有机化合物的存在.
更多相关视频
09:04Identifying Per- and Polyfluorinated Chemical Species with a Combined Targeted and Non-Targeted-Screening High-Resolution Mass Spectrometry Workflow
Published on: April 18, 2019
12.5K
07:12Author Spotlight: Quantification of Complex Lipidomic Samples Using Stable Isotope Labeling
Published on: August 23, 2024
1.3K
相关概念视频
High-Performance Liquid Chromatography: Types of Detectors
617
The role of the detectors in High-Performance Liquid Chromatography (HPLC) is to analyze the solutes as they exit from the chromatographic column. The detector recognizes the solute's property and generates corresponding electrical signals, which are converted into a readable graph of the detector's response versus elution time called a chromatogram at the computer. There are several types of HPLC detectors, each with its own advantages and limitations, depending on the analyte...
617
Gas Chromatography: Types of Detectors-II
416
In gas chromatography, different detectors are employed to meet specific analytical needs. These detectors are often categorized based on their detection mechanisms and the types of compounds they are best suited to analyze. Thermal Conductivity Detectors (TCD), Flame Ionization Detectors (FID), and Electron Capture Detectors (ECD) represent common categories, each with unique operating principles and applications. However, beyond these, several other detectors are designed for more specialized...
416
Mass Spectrometry: Complex Analysis
825
Mass spectrometry is an important technique for the identification of pure compounds. However, it has some limitations for the analysis of complex mixtures, often due to excessive fragmentation making the spectrum too complicated to decipher. Mass spectrometry can be combined with suitable separation methods in sequence, forming hyphenated methods, which are useful in the analysis of complex mixtures.
GC–MS is a powerful hyphenated method commonly used in forensics and environmental...
GC–MS is a powerful hyphenated method commonly used in forensics and environmental...
825
